(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
Identifieur interne : 001D70 ( Main/Exploration ); précédent : 001D69; suivant : 001D71(N-Phenylthiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
Auteurs : Sofia Mekarat [Thaïlande] ; Chaveng Pakawatchai [Thaïlande] ; Saowanit Saithong [Thaïlande]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the AgI atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetramers (two cations and two anions), which feature
Url:
DOI: 10.1107/S1600536814014147
PubMed: 25161537
PubMed Central: 4120613
Affiliations:
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90112,<country>Thailand</country></nlm:aff><country xml:lang="fr">Thaïlande</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saithong, Saowanit" sort="Saithong, Saowanit" uniqKey="Saithong S" first="Saowanit" last="Saithong">Saowanit Saithong</name><affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112,<country>Thailand</country></nlm:aff><country xml:lang="fr">Thaïlande</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">25161537</idno><idno type="pmc">4120613</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120613</idno><idno type="RBID">PMC:4120613</idno><idno type="doi">10.1107/S1600536814014147</idno><date 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sort="Pakawatchai, Chaveng" uniqKey="Pakawatchai C" first="Chaveng" last="Pakawatchai">Chaveng Pakawatchai</name><affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112,<country>Thailand</country></nlm:aff><country xml:lang="fr">Thaïlande</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Saithong, Saowanit" sort="Saithong, Saowanit" uniqKey="Saithong S" first="Saowanit" last="Saithong">Saowanit Saithong</name><affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112,<country>Thailand</country></nlm:aff><country xml:lang="fr">Thaïlande</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2014">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title salt, [Ag(C<sub>7</sub>H<sub>8</sub>N<sub>2</sub>S)(C<sub>18</sub>H<sub>15</sub>P)<sub>2</sub>]NO<sub>3</sub>, the coordination geometry about the Ag<sup>I</sup> atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N—H⋯O hydrogen bonds, generating tetramers (two cations and two anions), which feature <italic>R</italic><sub>2</sub><sup>2</sup>(8) and <italic>R</italic><sub>4</sub><sup>4</sup>(8) loops. The cations are linked by weak C—H⋯π interactions, generating a three-dimensional network.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>Thaïlande</li></country></list><tree><country name="Thaïlande"><noRegion><name sortKey="Mekarat, Sofia" sort="Mekarat, Sofia" uniqKey="Mekarat S" first="Sofia" last="Mekarat">Sofia Mekarat</name></noRegion><name sortKey="Pakawatchai, Chaveng" sort="Pakawatchai, Chaveng" uniqKey="Pakawatchai C" first="Chaveng" last="Pakawatchai">Chaveng Pakawatchai</name><name sortKey="Saithong, Saowanit" sort="Saithong, Saowanit" uniqKey="Saithong S" first="Saowanit" last="Saithong">Saowanit Saithong</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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